Hi Gao ,
Thanks for sending those data through. You are correct that this is an issue because only the m/z is reported in the PE files. iolite was automatically assigning the first element that matched the mass. I have updated iolite's code to assign m/z 204 to Pb. That change will be available in the next release of iolite (>v4.5.5.1).
In the meantime, to change the channel details, you can just paste the following lines into iolite's Python Workspace and run them:
pb = data.timeSeries("Hg204")
pb.setProperty("Element", "Pb")
pb.name = "Pb204"
data.emitDataChanged()
That will change the Hg204 channel to Pb204.
Please let me know if you have any troubles.
Best regards,
Bence